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IBDP Chemistry HL Predicted Paper 1B sample

Questions

Question 1

A mixture of two miscible liquids K and M with close boiling points is separated using the apparatus shown in the figure below.

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Part a
[3]

Label the parts indicated S, T and U.

Part b
[1]

State the purpose of the fractionating column packed with glass beads.

Part c
[2]

Explain why fractional distillation is preferred to simple distillation for separating K and M.

Part d
[2]

K has the lower boiling point. Predict which component (K or M) is collected first and justify your answer.

Part e
[2]

Explain why, for two isomers of similar molar mass, a more highly branched isomer tends to distill first. Refer to intermolecular forces/volatility.

Part f
[2]

After collecting a fraction believed to be an alcohol, identify one diagnostic IR absorption that would confirm the presence of an –OH group and one that would distinguish an aldehyde/ketone by their C=O group. Give typical wavenumber ranges.

[12]

Question 2

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